When your last Shadow Form ends and your stood there with an enchantment... your EXTREMELY likely to be blasted by a Shatter Enchantments. I also think it would only actually work if the damage you took wasn't enough to kill you. That and again, the AoE hits from Surge, Inferno, Pheonix, etc would all activate it early.
Also you'd be nothing more than fragbait in the spider cave. I still say your best bet is Vital Boon/Pious Haste or Signet of Pious Light, there wouldn't be any time to shatter it if used well.
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